Abstract
Very few studies have reported the presence of the organophosphate esters (OPEs) in African indoor microenvironments. We therefore document here, the concentrations, profiles, and human exposure to eight organophosphate esters (OPEs) for the first time in indoor dust from various microenvironments in Nigeria, specifically: cars/buses (n = 10), homes (n = 20), offices (n = 20), and medical centres (n = 14). The concentrations of OPEs in these indoor dust samples were among the lowest reported internationally. Concentrations of ∑8OPEs varied substantially between individual samples and the predominant OPEs were: tris(2-butoxyethyl) phosphate (TBOEP) (detection frequency (DF) = 90–100%), tris(1-chloro-2-propyl) phosphate (TCIPP) (DF = 100%), and 2-ethylhexyl-diphenyl phosphate (EHDPP) (DF = 100%). There were no significant differences (P˃0.05) between ∑8OPEs concentrations in dust samples from cars/buses (average = 295 ng/g), offices (231 ng/g), homes (277 ng/g), and medical centres (127 ng/g). Concentrations of chlorinated OPEs: tris(2-chloroethyl) phosphate (TCEP), TCIPP, and tris(1,3-dichloro-2-propyl) phosphate (TDCIPP) were significantly correlated with those of triphenyl phosphate (TPhP), EHDPP, and TBOEP. Estimated daily intakes (EDI) of target OPEs via indoor dust ingestion and dermal absorption were lower than the corresponding reference dose (RfD) values, indicating that exposure to the studied OPEs in the indoor environment does not pose a significant health risk for the general population in Nigeria, even under a high-end exposure scenario.
Original language | English |
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Article number | 100208 |
Number of pages | 9 |
Journal | Emerging Contaminants |
Volume | 9 |
Issue number | 2 |
Early online date | 25 Jan 2023 |
DOIs | |
Publication status | Published - Jun 2023 |
Bibliographical note
Funding Information:The authors would like to acknowledge the Petroleum Technology Development Fund for the award of a scholarship to Muideen Gbadamosi ( PTDF scholar ID: 1382 ). They also acknowledge the support of the postgraduate and undergraduate students of the Department of Chemical Sciences, Tai Solarin University of Education , 2021 set, Ogun State, Nigeria for helping with the collection of indoor dust samples.
Keywords
- Africa
- Homes
- Indoor dust
- Medical centres
- Offices
- Organophosphate esters
- Vehicles
ASJC Scopus subject areas
- Toxicology
- Public Health, Environmental and Occupational Health
- Health, Toxicology and Mutagenesis