Enhanced Compatibility of Secondary Waste Carbon Fibers through Surface Activation via Nanoceramic Coating in Fiber-Reinforced Cement Mortars

Matteo Sambucci*, Marco Valente, Seyed Mostafa Nouri, Mehdi Chougan, Seyed Hamidreza Ghaffar

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

The utilization of waste fibers in the production of reinforced concrete materials offers several advantages, including reducing environmental strain and socio-economic impacts associated with composite waste, as well as enhancing material performance. This study focuses on the development of cementitious mortars using secondary waste carbon fibers, which are by-products derived from the industrial conversion of recycled fibers into woven/non-woven fabrics. The research primarily addresses the challenge of achieving adequate dispersion of these recycled fibers within the matrix due to their agglomerate-like structure. To address this issue, a deagglomeration treatment employing nanoclay conditioning was developed. The functionalization with nanoclay aimed to promote a more uniform distribution of the reinforcement and enhance compatibility with the cementitious matrix. Various fiber weight percentages (ranging from 0.5 w/w% to 1 w/w% relative to the cement binder) were incorporated into the fiber-reinforced mix designs, both with and without nanoceramic treatment. The influence of the reinforcing fibers and the compatibility effects of nanoclay were investigated through a comprehensive experimental analysis that included mechanical characterization and microstructural investigation. The effectiveness of the nanoceramic conditioning was confirmed by a significant increase in flexural strength performance for the sample incorporating 0.75 w/w% of waste fibers, surpassing 76% compared to the control material and exceeding 100% compared to the fiber-reinforced mortar incorporating unconditioned carbon fibers. Furthermore, the addition of nanoclay-conditioned carbon fibers positively impacted compression strength performance (+13% as the maximum strength increment for the mortar with 0.75 w/w% of secondary waste carbon fibers) and microstructural characteristics of the samples. However, further investigation is required to address challenges related to the engineering properties of these cementitious composites, particularly with respect to impact resistance and durability properties.

Original languageEnglish
Article number1466
Number of pages24
JournalCoatings
Volume13
Issue number8
DOIs
Publication statusPublished - 20 Aug 2023

Bibliographical note

Funding Information:
This research was supported by the “Avvio alla Ricerca—Tipo 2” funding program provided by Sapienza University of Rome to Dr. Matteo Sambucci. The title of the research project is: Compositi sandwich a matrice cementizia: ottimizzazione delle caratteristiche meccaniche e di isolamento termo-acustico attraverso l’uso di materiali di riciclo derivanti dal recupero di pneumatici a fine vita (no. AR222181627BFECA).

Publisher Copyright:
© 2023 by the authors.

Keywords

  • carbon fiber recycling
  • fiber surface activation
  • fiber-reinforced cement composites
  • mechanical properties
  • nanoclay
  • secondary waste carbon fibers

ASJC Scopus subject areas

  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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